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ABSTRACT The low-J rotational transitions of 12CO are commonly used to trace the distribution of molecular gas in galaxies. Their ratios are sensitive to excitation and physical conditions in the molecular gas. Spatially resolved studies of CO ratios are still sparse and affected by flux calibration uncertainties, especially since most do not have high angular resolution or do not have short-spacing information and hence miss any diffuse emission. We compare the low-J CO ratios across the disc of two massive, star-forming spiral galaxies NGC 2903 and NGC 3627 to investigate whether and how local environments drive excitation variations at GMC scales. We use Atacama Large Millimeter Array (ALMA) observations of the three lowest-J CO transitions at a common angular resolution of 4 arcsec (190 pc). We measure median line ratios of $$R_{21}=0.67^{+0.13}_{-0.11}$$, $$R_{32}=0.33^{+0.09}_{-0.08}$$, and $$R_{31}=0.24^{+0.10}_{-0.09}$$ across the full disc of NGC 3627. We see clear CO line ratio variation across the galaxy consistent with changes in temperature and density of the molecular gas. In particular, towards the centre, R21, R32, and R31 increase by 35  per cent, 50  per cent, and 66  per cent, respectively, compared to their average disc values. The overall line ratio trends suggest that CO(3–2) is more sensitive to changes in the excitation conditions than the two lower J transitions. Furthermore, we find a similar radial R32 trend in NGC 2903, albeit a larger disc-wide average of $$\langle R_{32}\rangle =0.47^{+0.14}_{-0.08}$$. We conclude that the CO low-J line ratios vary across environments in such a way that they can trace changes in the molecular gas conditions, with the main driver being changes in temperature. 

We present new HCN and HCO⁺(J= 3–2) images of the nearby star-forming galaxies (SFGs) NGC 3351, NGC 3627, and NGC 4321. The observations, obtained with the Morita ALMA Compact Array, have a spatial resolution of ∼290–440 pc and resolve the innerR_gal ≲ 0.6–1 kpc of the targets, as well as the southern bar end of NGC 3627. We complement this data set with publicly available images of lower excitation lines of HCN, HCO⁺, and CO and analyse the behaviour of a representative set of line ratios: HCN(3–2)/HCN(1–0), HCN(3–2)/HCO⁺(3–2), HCN(1–0)/CO(2–1), and HCN(3–2)/CO(2–1). Most of these ratios peak at the galaxy centres and decrease outwards. We compare the HCN and HCO⁺observations with a grid of one-phase, non-local thermodynamic equilibrium (non-LTE) radiative transfer models and find them compatible with models that predict subthermally excited and optically thick lines. We study the systematic variations of the line ratios across the targets as a function of the stellar surface density (Σ_star), the intensity-weighted CO(2–1) (⟨I_CO⟩), and the star formation rate surface density (Σ_SFR). We find no apparent correlation with Σ_SFR, but positive correlations with the other two parameters, which are stronger in the case of ⟨I_CO⟩. The HCN/CO–⟨I_CO⟩ relations show ≲0.3 dex galaxy-to-galaxy offsets, with HCN(3–2)/CO(2–1)–⟨I_CO⟩ being ∼2 times steeper than HCN(1–0)/CO(2–1). In contrast, the HCN(3–2)/HCN(1–0)–⟨I_CO⟩ relation exhibits a tighter alignment between galaxies. We conclude that the overall behaviour of the line ratios cannot be ascribed to variations in a single excitation parameter (e.g., density or temperature). 

The complex physical, kinematic, and chemical properties of galaxy centres make them interesting environments to examine with molecular line emission. We present new 2 − 4″ (∼75 − 150 pc at 7.7 Mpc) observations at 2 and 3 mm covering the central 50″ (∼1.9 kpc) of the nearby double-barred spiral galaxy NGC 6946 obtained with the IRAM Plateau de Bure Interferometer. We detect spectral lines from ten molecules: CO, HCN, HCO + , HNC, CS, HC 3 N, N 2 H + , C 2 H, CH 3 OH, and H 2 CO. We complemented these with published 1 mm CO observations and 33 GHz continuum observations to explore the star formation rate surface density Σ SFR on 150 pc scales. In this paper, we analyse regions associated with the inner bar of NGC 6946 – the nuclear region (NUC), the northern (NBE), and southern inner bar end (SBE) and we focus on short-spacing corrected bulk (CO) and dense gas tracers (HCN, HCO + , and HNC). We find that HCO + correlates best with Σ SFR , but the dense gas fraction ( f dense ) and star formation efficiency of the dense gas (SFE dense ) fits show different behaviours than expected from large-scale disc observations. The SBE has a higher Σ SFR , f dense , and shocked gas fraction than the NBE. We examine line ratio diagnostics and find a higher CO(2−1)/CO(1−0) ratio towards NBE than for the NUC. Moreover, comparison with existing extragalactic datasets suggests that using the HCN/HNC ratio to probe kinetic temperatures is not suitable on kiloparsec and sub-kiloparsec scales in extragalactic regions. Lastly, our study shows that the HCO + /HCN ratio might not be a unique indicator to diagnose AGN activity in galaxies.